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- Besoins en NADPH, H+ supérieurs à ceux en ribose-5-phosphateo Tissus adipeux (AG), globules rouges (glutathion)o Transformation du ribulose-5-phosphate en glucose-6-phosphate (via segment non-oxydatif) Puis production de NADPH, H+ par le segment oxydatif (grâce au glucose-6-phosphate nouvellement formé)- Besoins en ribose-5-phosphate supérieurs à ceux en NADPH, H+ o Synthèse de nucléotides (cellules à multiplication rapide) o Inversion du sens du segment non oxydatif Transformation du glucose-6-phosphate en fructose-6-phosphate Formation de ribose-5-phosphate par le segment non oxydatif

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